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【ネットストア】カレンダー全品ポイント最大10倍キャンペーン

インプレス カレンダー・手帳・年賀状素材集 ポイント最大10倍キャンペーン(~12/31)

目次

  • 1 About the Author
    • 1.1 Research on Organoborane Chemistry
    • 1.2 Sketch of Professor Akira Suzuki’s Life
    • 1.3 Awards
    • 1.4 List of Publications(1967−2003)
  • 2 Organoboranes as Sources of Organic Radicals
    • 2.1 Introduction
    • 2.2 Reactions with α,β−Unsaturated Carbonyl Compounds
    • 2.3 Oxygen‐Induced Reaction of Trialkylboranes with Alkyl Halides.A Facile Coupling of Allylic and Benzylic Halides via Triethylborane
    • 2.4 A New Four‐Carbon‐Atom Homologation Involving the Free‐Radical Chain Reaction of 1,3−Butadiene Monoxide with Organoboranes
    • 2.5 Two Novel Reactions of Monomeric Formaldehyde with Trialkylboranes.A Remarkable Rapid Elimination Diverted by Oxygen to a Free‐Radical Chain Addition
    • 2.6 A Convenient Synthesis of α−Bromoketones from Vinyloxyboranes Obtained by the Reaction of Organoboranes with α,β−Unsaturated Ketones in the Presence of a Catalytic Amount of Oxygen
    • 2.7 Oxygen‐Induced 1,4−Addition Reaction of Organoboranes to Crotonaldimine
    • 2.8 Reaction of Organoboranes with 1−Acyl−2−vinylcyclopropanes in the Presence of Oxygen
    • 2.9 Reaction of Organoboranes with d‐Carvone and l‐Perilialdehyde in the Presence of Oxygen.Evidence for Coordination between Organoboranes and α,β−Unsaturated Carbonyl Oxygen in their Oxygen‐Induced Free‐Radical Reaction Process
    • 2.10 Reaction of Organoboranes with Iron(Ⅲ)Azide in the Presence of Hydrogen Peroxide.A Novel Synthesis of Azidoalkanes
  • 3 Organic Syntheses Using Organoborates
    • 3.1 Introduction
    • 3.2 Preparation of Tetracoordinate Organoborates
    • 3.3 Synthesis via Organoborates(R3B−X−Y)with Latent Leaving Groups(Y)in the α−Position
    • 3.4 Synthesis via Alkynylborates and Alkenylborates
    • 3.5 Synthesis via Copper(Ⅰ)Tetraorganoborates and Related Compounds
    • 3.6 Miscellaneous Reactions
    • 3.7 Summary
  • 4 Haloboration of 1−Alkynes and Its Synthetic Application
    • 4.1 Introduction
    • 4.2 Organic Synthesis via Haloboration Adducts Prepared from B−Halo−9−BBN
    • 4.3 Organic Synthesis via Haloboration Adducts Prepared from Tribromoborane
    • 4.4 Conclusion
  • 5 Palladium‐Catalyzed Cross‐Coupling Reactions of Organoboron Compounds with Organic Electrophiles
    • 5.1 Introduction
    • 5.2 Synthesis of Organoboron Reagents
    • 5.3 Palladium‐Catalyzed Reactions of Organoboron Compounds Their Mechanism
    • 5.4 Cross‐Coupling Reaction
    • 5.5 Head‐to‐Tail Coupling
    • 5.6 Carbonylative Coupling
    • 5.7 Alkoxycarbonylation and Dimerization
    • 5.8 Conclusion